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methyl [2-({[tert-butyl(dimethyl)silyl]oxy}methyl)-1-(4-methylphenyl)cycloprop-2-en-1-yl] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1000702-75-9

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1000702-75-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1000702-75-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,0,0,7,0 and 2 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1000702-75:
(9*1)+(8*0)+(7*0)+(6*0)+(5*7)+(4*0)+(3*2)+(2*7)+(1*5)=69
69 % 10 = 9
So 1000702-75-9 is a valid CAS Registry Number.

1000702-75-9Downstream Products

1000702-75-9Relevant academic research and scientific papers

Remarkable stereoelectronic control in the lewis base assisted [2,3]-rearrangement of cyclopropenylmethyl phosphinites

Rubina, Marina,Woodward, Eric W.,Rubin, Michael

, p. 5501 - 5504 (2008/09/18)

A novel 2,3-rearrangement of cyclopropenylmethyl phosphinites to methylenecyclopropylphosphine oxides was demonstrated. It was found that, in striking contrast to the analogous rearrangement known for nonstrained allylic systems, this reaction does not proceed at all upon thermal activation; however, it can be efficiently mediated by Lewis bases. Unique stereoelectronic effects control the diastereoselectivity of this transformation, leading to predominant formation of the more sterically hindered products.

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