1000992-62-0Relevant academic research and scientific papers
Copper-Catalyzed C(sp)-C(sp3) Coupling of Terminal Alkynes with Alkylsilyl Peroxides via a Radical Mechanism
Sakamoto, Ryu,Kato, Terumasa,Sakurai, Shunya,Maruoka, Keiji
supporting information, p. 1400 - 1403 (2018/03/09)
A copper-catalyzed C(sp)-C(sp3) coupling reaction between terminal alkynes and alkylsilyl peroxides is reported. In the presence of a copper catalyst and 4-dimethylaminopyridine, the reaction smoothly affords a variety of internal alkynes by co
Gold-catalyzed intramolecular carbocyclization of alkynyl ketones leading to highly substituted cyclic enones
Jin, Tienan,Yamamoto, Yoshinori
, p. 5259 - 5262 (2008/09/17)
(Chemical Equation Presented) The reaction of the internal alkynyl ketones 1 (n = 1) under the combined catalyst, AuCl3 and AgSbF6, gave the enones 2 in good to high yields, whereas that of the terminal alkynyl ketones 1 (n = 0) unde
