1000992-74-4Relevant academic research and scientific papers
Gold-catalyzed synthesis of carbon-bridged medium-sized rings
Barabe, Francis,Betournay, Genevieve,Bellavance, Gabriel,Barriault, Louis
supporting information; experimental part, p. 4236 - 4238 (2009/12/31)
Bicyclo[m.n.1]alkenone frameworks possessing quaternary carbon centers adjacent to a bridged ketone are frequently found in bioactive natural products. Although several methods have been developed to construct such frameworks, most of them are specific to a particular scaffold. Herein, we report a mild and highly efficient method to generate carbon-bridged frameworks of various sizes using phosphlno gold(I) catalysts.
