1000995-59-4

Upstream product

• 1206-41-3 N-(2-methylallyl)-4-toluenesulfonamide 
• 66303-63-7 (2-cyclopropylallyl) 4-toluenesulfonate 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 1000995-53-8 N-(2-cyclopropyl-2-oxoethyl)-N-(2-oxopropyl)-4-toluenesulfonamide 

Relevant academic research and scientific papers

Reaction of α-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] cycloaddition or [3+2] cycloaddition?

Chemical Equation Presented Exposure of α-ene-VCPs to catalytic [Rh(dppm)]SbF6 led to the discovery of a novel Rh(l)-catalyzed [3+2] reaction, which was shown to be efficient for the construction of 5/6- and 5/7-bicyclic compounds rather than the anticipated type IL [5+2] products.

Samarium(ii) iodide-mediated intramolecular pinacol coupling reactions with cyclopropyl ketones

The first reported intramolecular pinacol coupling of cyclopropyl ketones has been achieved, demonstrating that cyclisation competes favourably with ring-opening of the cyclopropyl ketyl radical. The Royal Society of Chemistry.