100100-72-9

Upstream product

• 38183-78-7 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitromethyl-α-D-ribo-hexopyranoside 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 99967-15-4 Methyl-4,6-O-benzyliden-2,3-didesoxy-3-iod-3-C-<(methoxy)(methoxycarbonylamino)methyl>-α-D-ribo-hexopyranosid 
• 100020-19-7 (E)-Methyl-4,6-O-benzyliden-2,3-didesoxy-3-C-methoxymethylen-α-D-erythro-hexopyranosid 
• 99967-16-5 (3R)-Methyl-4,6-O-benzyliden-3-C-cyan-2,3-didesoxy-α-D-erythro-hexopyranosid 
• 100100-71-8 (3S)-Methyl-4,6-O-benzyliden-2,3-didesoxy-3-C-formyl-α-D-erythro-hexopyranosid 

Downstream Products

• 120401-28-7 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-<4-(1,3-dioxan-2-yl)-1-butenyl>-α-D-arabino-hexopyranoside 
• 63593-10-2 (4aR,6S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-8-carbaldehyde 

Relevant academic research and scientific papers

THE SYNTHESIS OF C-FORMYL, BRANCHED-CHAIN CARBOHYDRATE DERIVATIVES BY THE CONVERSION OF NITROMETHYL GROUPS INTO CARBONYL GROUPS

Addition of the sodium salts of five branched-chain nitromethyl sugars in N,N-dimethylformamide to aqueous solutions of titanium(III) chloride (at pH 1) produced the respective, C-formyl, branched-chain carbohydrate derivatives 3-C-formyl-1,2:5,6-di-O-iso