100108-94-9Relevant academic research and scientific papers
STEREOSELECTIVE ALDOL ADDITIONS TO α-ALKOXY ALDEHYDES USING THIOESTER SILYL KETENE ACETALS.
Gennari, Cesare,Bernardi, Anna,Poli, Giovanni,Scolastico, Carlo
, p. 2373 - 2376 (1985)
Relative stereochemistry (chelation) effectively controls internal stereochemistry (syn-anti) in the addition of thiopropionate equivalents to O-benzyl lactic aldehyde.
LEWIS ACID MEDIATED ALDOL CONDENSATIONS USING THIOESTER SILYL KETENE ACETALS
Gennari, Cesare,Beretta, M. Grazia,Bernardi, Anna,Moro, Giorgio,Scolastico, Carlo,Todeschini, Roberto
, p. 893 - 910 (2007/10/02)
BF3-OEt2 mediated thioester silylketene acetal additions to aldehydes are stereoconvergent and give high anti-syn ratios and good chemical yields.An acyclic transition state model was hypothesized in order to account for the observed selectivity.Theoretic
