1001188-06-2

Upstream product

• 1001099-07-5 2-[(1'Z,3'E)-5'-(tert-butyldiphenylsilyloxy)-3'-methylpenta-1',3'-dien-1'-yl]-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane 
• 256518-38-4 (1E,3E)-2-methyl-1-[(trifluoromethanesulfonyl)oxy]-4-(2,6,6-trimethylcyclohex-1-en-1-yl)buta-1,3-diene 
• 138846-06-7 2-[(1’E,3’E)-3’-methyl-4’-iodobuta-1’,3’-dien-1’yl]-1,3,3-trimethylcyclohex-1-ene 

Downstream Products

• 22737-96-8 11-cis-retinol 

Relevant academic research and scientific papers

Highly convergent, stereospecific synthesis of 11-cis-retinoids by metal-catalyzed cross-coupling reactions of (Z)-1-alkenylmetals

(Chemical Equation Presented) A stereospecific synthesis of 11-cis-retinoids has as its key step the hitherto unexplored palladium-catalyzed cross-coupling of trans-tnenyl electrophiles and (1Z,3E)-penta-1,3-dienyl boronates (a Suzuki-Miyaura reaction) or