1001389-22-5Relevant academic research and scientific papers
Synthesis and reactivity of NiII(Phpy)2 (Phpy = 2-phenylpyridine)
Higgs, Andrew T.,Zinn, Paul J.,Sanford, Melanie S.
, p. 5446 - 5449 (2010)
This article describes the synthesis and reactivity of Ni II(Phpy)2 (Phpy = 2-phenylpyridine) with a variety of oxidants, including O2, Br2, PhICl2, N-fluoropyridinium salts, CuII salts, and N-halosuccinimides. High-oxidation-state Ni intermediates were not detected in any of these transformations. In all cases, the major organic product resulted from oxidatively induced C-C bond formation to generate the Phpy-Phpy dimer. Traces (2-16%) of organic products resulting from C-O, C-Br, C-Cl, and C-N bond-forming reductive elimination were also observed.
Rhodium(III)-catalyzed C-H activation and amidation of arenes using N -arenesulfonated imides as amidating reagents
Yu, Songjie,Wan, Boshun,Li, Xingwei
supporting information, p. 3706 - 3709 (2013/08/15)
Rhodium(III)-catalyzed C-H activation-amidation of arenes bearing chelating groups has been achieved using N-arenesulfonated imides as efficient amidating reagents without using any base additive. Pyridine, oxime, and pyrimidine proved to be viable direct
