1001437-09-7

Basic information

• Product Name: (S)-2-(benzhydrylidene-amino)-1-bromo-4-methylpentane
• Synonyms: (S)-2-(benzhydrylidene-amino)-1-bromo-4-methylpentane
• CAS NO: 1001437-09-7
• Molecular Weight: 344.294
• Mol File: 1001437-09-7.mol

Chemical Properties

• CAS DataBase Reference: (S)-2-(benzhydrylidene-amino)-1-bromo-4-methylpentane(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-(benzhydrylidene-amino)-1-bromo-4-methylpentane(1001437-09-7)
• EPA Substance Registry System: (S)-2-(benzhydrylidene-amino)-1-bromo-4-methylpentane(1001437-09-7)

Safety Data

• Hazardous Substances Data: 1001437-09-7(Hazardous Substances Data)

Upstream product

• 1013-88-3 Benzophenone imine 
• 13892-89-2 (S)-1-(bromomethyl)-3-methylbutylammonium bromide 

Relevant articles and documents

Synthesis of chiral iminoalkyl functionalised N-heterocyclic carbenes and their use in asymmetric catalysis

A library of new chiral iminoalkyl imidazolium salts has been synthesised from amino acids using a modular design approach. Deprotonation with silver oxide yields silver carbene transfer reagents, which can be used as ligand sources in asymmetric catalysis. Preliminary testing has shown that the ligands induce enantioselectivity in the palladium-catalysed allylic alkylation of 1,3-diphenylprop-3-enyl acetate with dimethyl malonate.