100154-13-0

Basic information

• Product Name: {Rh(C₁₀H₈N₂)2(OH)2}⁽¹⁺⁾
• Synonyms: {Rh(C₁₀H₈N₂)2(OH)2}⁽¹⁺⁾
• CAS NO: 100154-13-0
• Molecular Weight: 449.294
• Mol File: 100154-13-0.mol

Chemical Properties

• CAS DataBase Reference: {Rh(C₁₀H₈N₂)2(OH)2}⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: {Rh(C₁₀H₈N₂)2(OH)2}⁽¹⁺⁾(100154-13-0)
• EPA Substance Registry System: {Rh(C₁₀H₈N₂)2(OH)2}⁽¹⁺⁾(100154-13-0)

Safety Data

• Hazardous Substances Data: 100154-13-0(Hazardous Substances Data)

Upstream product

• 1127227-64-8 tris(2,2'-bipyridine)rhodium(III) 

Relevant articles and documents

Mechanism of the Formation of Dihydrogen from the Photoinduced Reactions of Poly(pyridine)ruthenium(II) and Poly(pyridine)rhodium(III) Complexes

The irradiation of Ru(bpy)32+, Rh(bpy)33+, and triethanolamine (TEOA) solutions 109 8, 25 deg C) with 450 +/- 20-nm light yields rhodium (I) (Φ = 0.13 +/- 0.02) (units for Φ in mol einstein-1 throughout the paper) and dihydrogen (Φ = 0.11 +/- 0.02) in the absence and presence of platinum, respectively.A detailed mechanistic scheme has been deduced from the results of continuous- and flash-photolysis experiments: light absorption by Ru(bpy)32+ gives the excited state (*)Ru(bpy)32+ which is oxidized by Rh(bpy)33+ (k = 3.9*108 M-1 s-1) yielding Ru(bpy)33+ and Rh(bpy)32+ with a cage escape yield of 0.15 +/- 0.03.Back-reaction of Ru(bpy)33+ with Rh(bpy)32+ (k = 3*109 M-1 s-1) is prevented by reduction of Ru(bpy)33+ by TEOA (k = 0.2*108 M-1 s-1) The oxidized TEOA radical so generated undergoes a TEOA-promoted rearrangement (k = 0.3*107 M-1 s-1) to a reducing radical.The latter reduces Rh(bpy)32+ so that the net yield for Rh(bpy)32+ formation is 0.3 +/- 0.1.Rate-determining loss of bpy from Rh(bpy)32+ (k = 1.0 +/-0.5 s-1) is followed by rapid reduction of Rh(bpy)22+ by Rh(bpy)32+ (k = 0.3* 109 M-1 s-1) giving Rh(bpy)33+ and Rh(I).In the presence of platinum, H2 is formed at the expense of Rh(I); catalyzed reaction of Rh(II) with water occurs before disproportionation to Rh(I) can take place.The H2 quantum yield in this system is limited only by the cage escape of the primary products, the homogeneous and heterogeneous dark reactions being very efficient.In the course of this study the electrochemistry of Rh(bpy)33+, Rh(phen)33+, and Rh(bpy)2(OH)2+ in aqueous solution was investigated, and the quenching of Ru(bpy)32+ emission by these Rh(III) complexes was characterized.