100157-26-4

Basic information

• Product Name: Neorustmicin A
• Synonyms: Neorustmicin A
• CAS NO: 100157-26-4
• Molecular Formula: C21H32 O5
• Molecular Weight: 364.48
• Mol File: 100157-26-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 546.6°Cat760mmHg
• Flash Point: 185.3°C
• Appearance: /
• Density: 1.09g/cm³
• Vapor Pressure: 3.15E-14mmHg at 25°C
• Refractive Index: 1.518
• CAS DataBase Reference: Neorustmicin A(CAS DataBase Reference)
• NIST Chemistry Reference: Neorustmicin A(100157-26-4)
• EPA Substance Registry System: Neorustmicin A(100157-26-4)

Safety Data

• Hazardous Substances Data: 100157-26-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C21H32O5/c1-7-18-16(5)10-14(3)8-13(2)9-15(4)11-21(25,12-22)19(23)17(6)20(24)26-18/h9-10,13,17-18,22,25H,3,7-8,11-12H2,1-2,4-6H3/b15-9+,16-10+/t13-,17+,18-,21?/m0/s1

Upstream product

• 180062-76-4 (11E,16E)-(2R,5S,7R,10S,15S)-10-Ethyl-7,11,15,17-tetramethyl-13-methylene-2-(2,4,6-trimethyl-phenyl)-1,3,9-trioxa-spiro[4.13]octadeca-11,16-diene-6,8-dione 
• 179944-17-3 (11E,16E)-(2R,5S,7S,10S,15S)-10-Ethyl-7,11,15,17-tetramethyl-13-methylene-2-(2,4,6-trimethyl-phenyl)-1,3,9-trioxa-spiro[4.13]octadeca-11,16-diene-6,8-dione 
• 179944-06-0 [2-((E)-(S)-1-Ethyl-3-iodo-2-methyl-allyloxymethoxy)-ethyl]-trimethyl-silane 
• 179944-14-0 (2R,4S)-4-[(2E,7E)-(4S,9S)-2,4,8-Trimethyl-6-methylene-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dienyl]-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester 
• 179944-15-1 (2R,4S)-4-((2E,7E)-(4S,9S)-9-Acetoxy-2,4,8-trimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester 
• 179944-16-2 (11E,16E)-(2R,5S,10S,15S)-10-Ethyl-11,15,17-trimethyl-13-methylene-2-(2,4,6-trimethyl-phenyl)-1,3,9-trioxa-spiro[4.13]octadeca-11,16-diene-6,8-dione 
• 179944-20-8 (2R,4S)-4-((2E,7E)-(4S,9S)-9-Hydroxy-2,4,8-trimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester 
• 241823-02-9 (E)-(2S,7S)-1-(tert-Butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-7-(2-trimethylsilanyl-ethoxymethoxy)-non-5-en-4-ol 
• 241823-01-8 (2E,7E)-(4S,9S)-2,4,8-Trimethyl-6-methylene-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dien-1-ol 
• 179944-13-9 [2-((2E,7E)-(1S,6S)-1-Ethyl-9-iodo-2,6,8-trimethyl-4-methylene-nona-2,7-dienyloxymethoxy)-ethyl]-trimethyl-silane 
• 241823-00-7 (E)-(2S,7S)-2,6-Dimethyl-4-methylene-7-(2-trimethylsilanyl-ethoxymethoxy)-non-5-enal 
• 179944-18-4 (E)-(2S,7S)-2,6-Dimethyl-4-methylene-7-(2-trimethylsilanyl-ethoxymethoxy)-non-5-en-1-ol 
• 179944-05-9 (S)-3-(2-trimethylsilylethoxymethoxy)pentan-2-one 
• 179944-08-2 5-(tert-butyldimethylsilanyloxy)-4(S)-methylpentan-2-one 

Relevant articles and documents

A total synthesis of galbonolide B

(Chemical Equation Presented) An ester enolate rearrangement/silicon mediated fragmentation cascade was used to convert 7 and 8 into the alcohol 9. The alcohol 9 was converted into the allylic alcohol 12 and then to the ester 14. A further ester enolate r