1001653-41-3

Upstream product

• 6138-90-5 trans-geranyl bromide 
• 250358-84-0 (Z)-3-Phenylpent-2-en-4-in-1-ol 
• 1504-58-1 3-Phenyl-2-propyn-1-ol 
• 131692-90-5 (Z)-3-iodo-3-phenylprop-2-en-1-ol 
• 536-74-3 phenylacetylene 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 314734-23-1 (Z)-3-Phenyl-5-(trimethylsilyl)pent-2-en-4-in-1-ol 

Downstream Products

• 1001653-78-6 2-(2,6-dimethyl-2-vinyl-hept-5-enyl)-3-phenyl-furan 

Relevant academic research and scientific papers

Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers

A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions.

Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement

(Chemical Equation Presented) Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy forma