100185-10-2Relevant academic research and scientific papers
COMPOSES DU PHOSPHORE DICOORDONNE - ACTION DES ORGANOMAGNESIENS SUR LES DERIVES DU TRIAZAPHOSPHOLE-1,2,4,3: SYNTHESE DE DERIVES DE LA H-4 TRIAZAPHOSPHOLINE-1,2,4,3 ET MISE EN EVIDENCE DE L'EQUILIBRE DE SCHLENK
Haddad, M.,M'Pondo, Th. N'Gando,Malavaud, C.,Lopez, L.,Barrans, J.
, p. 333 - 346 (2007/10/02)
2,5-disubstituted 1,2,4,3-triazaphospholes - dicoordinated phosphorus compounds - react with organomagnesium halide, in ether, to give the corresponding triazaphospholinyl magnesium halides.Their hydrolysis, alcoholysis or hydrogen abstraction from suitable solvents afford the corresponding triazaphospholines which are easily sulfured.By intervention of the Schlenk equilibrium in benzene, we obtain a mixture of the triazaphosphonyl magnesium halide and a complex of the triazaphosphole reagent with magnesium halide occurring in the solution.Some properties of these new triazaphospholines were investigated.
