100201-09-0Relevant articles and documents
Dienediolates from Unsaturated Carboxylic Acids: Michael Addition of Dilithium Buta-1,3-diene-1,1-diolate (from Crotonic Acid) to Unsaturated Ketones
Ballester, Pablo,Costa, Antonio,Raso, Angel Garcia,Gomez-Solivellas, Antonio,Mestres, Ramon
, p. 1711 - 1718 (2007/10/02)
Conjugate addition of the lithium dienediolate derived from crotonic acid to several α,β-unsaturated ketones gave 7-oxocarboxylic acids.Styryl ketones (2a-g) afforded mixtures of 1,4-α- and 1,4-γ-adducts, in proportions depending on the bulk of the substi