100246-31-9

Basic information

• Product Name: 1-(allyloxy)-4-chloro-2-nitrobenzene
• Synonyms: 1-(allyloxy)-4-chloro-2-nitrobenzene
• CAS NO: 100246-31-9
• Molecular Weight: 213.62
• Mol File: 100246-31-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(allyloxy)-4-chloro-2-nitrobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(allyloxy)-4-chloro-2-nitrobenzene(100246-31-9)
• EPA Substance Registry System: 1-(allyloxy)-4-chloro-2-nitrobenzene(100246-31-9)

Safety Data

• Hazardous Substances Data: 100246-31-9(Hazardous Substances Data)

Upstream product

• 89-64-5 p-chloro-o-nitrophenol 
• 106-95-6 allyl bromide 

Downstream Products

• 851025-61-1 2-(allyloxy)-5-chlorobenzenamine 

Relevant articles and documents

Cyclizing radical carboiodination, carbotelluration, and carboaminoxylation of aryl amines

Radical carboiodination of various aryl amines is reported. Aryl diazonium salts, generated in situ from the corresponding aryl amines, are reacted with Bu4NI to provide the corresponding aryl radicals which undergo 5-exo or 6-exo cyclization. Iodine abstraction eventually affords the carboiodinated products in good to excellent yields. If TEMPO is added, the cascade provides the cyclized carboaminoxylation products. Running the reaction in the presence of PhTeTePh affords the phenyltellurated cyclized products.