100250-48-4Relevant academic research and scientific papers
Synthesis of α,α,β,β-Tetrasubstituted β-Lactones from Ketones, Ethyl α-Bromoisobutyrate, and Indium or Zinc. Factors Influencing the β-Lactone Formation in the Electrochemical and the Classical Procedure of the Reformatsky Reaction
Schick, Hans,Ludwig, Ralf,Schwarz, Karl-Heinz,Kleiner, Katharina,Kunath, Annamarie
, p. 3161 - 3164 (2007/10/02)
An efficient synthesis of α,α,β,β-tetrasubstituted β-lactones is achieved by an electrochemically supported Reformatsky reaction of aliphatic and aromatic ketones with ethyl α-bromoisobutyrate at a sacrificial indium anode.Under these conditions, in most
Electrochemical activation of zinc in the coupling reaction of α-bromoesters with carbonyl compounds
Rollin, Y.,Gebehenne, C.,Derien, S.,Dunach, E.,Perichon, J.
, p. 9 - 14 (2007/10/02)
The Reformatsky reaction has been examined using a mild and effective method of electrochemical zinc activation, based on the cathodic reduction of a catalytic amount of zing bromide in acetonitrile.
Hydrocarbonylating Cyclization of Dienes, 6. - Metal-Induced Skeletal Rearrangements during an Attempted Synthesis of the Acorane System from Substituted 1,1-Divinylcyclohexanes
Eilbracht, Peter,Acker, Michael,Huettmann, Gerd,Winkels, Irmgard
, p. 159 - 168 (2007/10/02)
In attempts of a regio- and stereoselective synthesis of the acorane skeleton 2, substituted 1,1-divinylcyclohexanes 1 were treated under the conditions of hydrocarbonylating cyclization.Substrates with higher degree of substitution surprisingly did not l
