1003-33-4Relevant academic research and scientific papers
REARRANGEMENT OF CYCLOPROPYL, SUBSTITUTED VINYL AND ALKYL GROUPS TO DIVALENT CARBON.
Kraska, A. R.,Cherney, L. I.,Shechter, H.
, p. 2163 - 2166 (2007/10/02)
The relative carbenic migratory abilities of cyclopropyl, β,β-dimethylvinyl, methyl,ethyl and isopropyl groups have been determined.
Mechanistic Aspects of Gas-Phase Photodecarbonylation Reactions of Bicyclohexanones
Mariano, Patrick S.,Bay, Elliott,Watson, Darrell G.,Rose, Timothy,Bracken, Christopher
, p. 1753 - 1762 (2007/10/02)
The gas-phase photodecarbonylation and photofragmentation reactions of substituted bicyclohexan-3-ones have been studied in detail.Photolysis of these ketones yields 1,3-dienes, vinylcyclopropanes, and 1,4-dienes as detectable products.The possible mechanisms for these reactions are discussed in light of the regiochemical and stereochemical results obtained.In addition, methyl substitution at C-6 and C-2 of these ketones has been shown to have a pronounced effect on both product ratios and overall reaction efficiency.These effects are discussed in terms of stereoelectronic and electronic controls of rates of cyclopropane ring opening of intermediate acylcyclopropylcarbinyl diradicals.
