1003323-26-9

Usage

Uses

Used in Pharmaceutical Synthesis:
[3,5-bis(methoxymethyl)pinacolboranebenzene] is used as a key intermediate in the synthesis of various pharmaceuticals. Its ability to function as a source of the boryl anion makes it a valuable component in the development of new drugs, contributing to the advancement of medical treatments.
Used in Agrochemical Production:
In the agrochemical industry, [3,5-bis(methoxymethyl)pinacolboranebenzene] is utilized as a building block for the creation of novel agrochemicals. Its involvement in organic synthesis allows for the development of innovative products that can enhance agricultural productivity and crop protection.
Used in Material Science:
[3,5-bis(methoxymethyl)pinacolboranebenzene] is also employed in the field of material science, where it is used as a component in the synthesis of new materials. Its unique properties and reactivity enable the development of advanced materials with specific characteristics, such as improved strength, durability, or functionality.
Used in Catalyst Development:
This chemical compound has been utilized in the development of new catalysts, which are essential for accelerating and controlling chemical reactions. [3,5-bis(methoxymethyl)pinacolboranebenzene] contributes to the advancement of catalytic processes, leading to more efficient and environmentally friendly chemical reactions.
Used as a Reagent in Organic Transformations:
[3,5-bis(methoxymethyl)pinacolboranebenzene] is used as a reagent in various organic transformations, where it aids in the conversion of one chemical compound to another. Its role in these processes is vital for the synthesis of complex organic substances and the development of new chemical products.

Upstream product

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Relevant academic research and scientific papers

Diorganoruthenium complexes incorporating noninnocent [C6H 2(CH2ER2)2-3,5]2 2-- (E = N, P) bis-pincer bridging ligands: Synthesis, spectroelectrochemistry, and DFT studies

The dinuclear complex [(tpy)RuII(PCP-PCP)RuII(tpy)] Cl2 (bridging PCP-PCP = 3,3′,5,5′- tetrakis(diphenylphosphinomethyl)biphenyl, [C6H2(CH 2PPh2)2-3,5]22-) was prepared via a transcyclometalation reaction of the bis-pincer ligand [PC(H)P-PC(H)P] and the Ru(II) precursor [Ru(NCN)(tpy)]Cl (NCN = [C 6H3(CH2NMe2)2-2,6] -) followed by a reaction with 2,2′:6′,2″- terpyridine (tpy). Electrochemical and spectroscopic properties of [(tpy)Ru II(PCP-PCP)RuII-(tpy)]Cl2 are compared with those of the closely related [(tpy)RuII(NCN-NCN)Ru II(tpy)](PF6)2 (NCN-NCN = [C6H 2(CH2-NMe2)2-3,5]2 2-) obtained by two-electron reduction of [(tpy)Ru III(NCN-NCN)RuIII(tpy)](PF6)4. The molecular structure of the latter complex has been determined by single-crystal X-ray structure determination. One-electron reduction of [(tpy)Ru III(NCN-NCN)RuIII(tpy)](PF6)4 and one-electron oxidation of [(tpy)RuII(PCP-PCP)RuII(tpy)] Cl2 yielded the mixed-valence species [(tpy)RuIII(NCN-NCN) RuII(tpy)]3+ and [(tpy)RuIII(PCP-PCP)Ru II(tpy)]3+, respectively. The comproportionation equilibrium constants Kc (900 and 748 for [(tpy)Ru III(NCN-NCN)RuIII(tpy)]4+ and [(tpy)Ru II(PCP-PCP)RuII(tpy)]2+, respectively) determined from cyclic voltammetric data reveal comparable stability of the [RuIII-RuII] state of both complexes. Spectroelectrochemical measurements and near-infrared (NIR) spectroscopy were employed to further characterize the different redox states with special focus on the mixed-valence species and their NIR bands. Analysis of these bands in the framework of Hush theory indicates that the mixed-valence complexes [(tpy)RuIII(PCP-PCP)RuII(tpy)]3+ and [(tpy)RuIII(NCN-NCN)RuII(tpy)]3+ belong to strongly coupled borderline Class II/Class III and intrinsically coupled Class III systems, respectively. Preliminary DFT calculations suggest that extensive derealization of the spin density over the metal centers and the bridging ligand exists. TD-DFT calculations then suggested a substantial MLCT character of the NIR electronic transitions. The results obtained in this study point to a decreased metal-metal electronic interaction accommodated by the double-cyclometalated bis-pincer bridge when strong σ-donor NMe 2 groups are replaced by weak σ-donor, π-acceptor PPh 2 groups.