100351-41-5

Basic information

• Product Name: MoH(CHC(CH₃)C(O)OC₆H₁₁)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2
• CAS NO: 100351-41-5
• Molecular Weight: 1061.02
• Mol File: 100351-41-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: MoH(CHC(CH₃)C(O)OC₆H₁₁)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: MoH(CHC(CH₃)C(O)OC₆H₁₁)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2(100351-41-5)
• EPA Substance Registry System: MoH(CHC(CH₃)C(O)OC₆H₁₁)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2(100351-41-5)

Safety Data

• Hazardous Substances Data: 100351-41-5(Hazardous Substances Data)

Upstream product

• 32109-09-4 [MoH₄(1,2-bis(diphenylphosphino)ethane)2] 
• 101-43-9 cyclohexyl methacrylate 

Relevant articles and documents

Selective activation of olefinic C-H bonds. Reaction of a hydridomolybdenum complex with methacrylic esters to form hydrido-alkenyl complexes

MoH4(dppe)2 (dppe = Ph2PCH2CH2PPh2) (1) reacted thermally or photochemically with an excess of alkyl methacrylates to give red complexes which analyzed as MoH[CH=C(CH3)C(O)OR] (dppe)2 (2, R = C2H5, i-C3H7, n-C4H9, and c-C6H11) together with H2 and alkyl isobutyrates. Seven-coordinate complexes 2 were spectroscopically characterized and were found to be stereochemically nonrigid on the basis of temperature-dependent 31P{1H} NMR spectra. The mechanism of the formation of 2 and its intramolecular exchange process are discussed.