10036-25-6 Usage
General Description
(1α,5α)-Bicyclo[3.3.1]nonan-2β-ol is a chemical compound with the molecular formula C9H16O. It is a bicyclic compound with a unique fused ring system, consisting of three carbon rings. The compound has two stereocenters, with a 1α- and 5α- configuration. It is classified as a bicyclic alcohol and is commonly used in organic synthesis and pharmaceutical research. The compound has potential medicinal and pharmacological applications due to its unique structural properties, and it also serves as a valuable intermediate in the synthesis of complex organic molecules. (1α,5α)-Bicyclo[3.3.1]nonan-2β-ol exhibits interesting stereochemistry and physical properties, making it an intriguing target for chemical and pharmaceutical studies.
Check Digit Verification of cas no
The CAS Registry Mumber 10036-25-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,3 and 6 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 10036-25:
(7*1)+(6*0)+(5*0)+(4*3)+(3*6)+(2*2)+(1*5)=46
46 % 10 = 6
So 10036-25-6 is a valid CAS Registry Number.
10036-25-6Relevant articles and documents
Fragmentierungsreaktionen an Carbonylverbindungen mit β-staendigen elektronegativen Substituenten, XXXIII 3-Oxatricyclo1,4>undec-4-en, ein stark gespannter Vierring-Enolether
Gerdes, Hero,Javeri, Shailaja,Marschall, Helga
, p. 1907 - 1920 (2007/10/02)
The behaviour of β-keto tosylates against nucleophiles has been investigated.The keto tosylate 6 underwent intramolecular cyclization with KOtBu in ether to produce exclusively the four-membered O-alkylated product 18 (the title compound).The substitution products 5 or 7 are obtained from 6 with NaOMe in methanol or KCN in DMSO, resp.Reaction of 6 with MeLi yielded the diol 13.The keto tosylate 31 reacted with MeLi analogously to form the diol 28, whereas with MeMgI a mixture of the Grob fragmentation product 33 and the alcohol 32 (via 28 by H2O elimination) was produced.Similarly keto tosylate 22b and MeMgI yielded the alcohol 27. - The non-enolizable keto tosylate 44 undergoes very slow reaction wih NaOH/MeOH to produce 41, 42, and 45 in low yield.
