10038-41-2

Basic information

• Product Name: Benzene, 1,1'-oxybis[2-(bromomethyl)-
• Synonyms: bis-(2-bromomethyl-phenyl) ether;2,2'-bis(bromomethyl)-1,1'-oxybisbenzene;2,2'-oxybis(bromomethyl)benzene;2,2'-bis(bromomethyl)-diphenyl ether;Benzene,1,1'-oxybis[2-(bromomethyl);2-bromomethyl-phenyl ether
• CAS NO: 10038-41-2
• Molecular Formula: C14H12Br2O
• Molecular Weight: 356.057
• Mol File: 10038-41-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-oxybis[2-(bromomethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-oxybis[2-(bromomethyl)-(10038-41-2)
• EPA Substance Registry System: Benzene, 1,1'-oxybis[2-(bromomethyl)-(10038-41-2)

Safety Data

• Hazardous Substances Data: 10038-41-2(Hazardous Substances Data)

Upstream product

• 10038-40-1 [oxybis(2,1-phenylene)]dimethanol 
• 95-48-7 ortho-cresol 
• 446-52-6 2-Fluorobenzaldehyde 
• 90-02-8 salicylaldehyde 
• 49590-51-4 2,2'-oxybis(benzaldehyde) 
• 101-84-8 diphenylether 
• 4731-34-4 2,2'-dimethyldiphenyl ether 
• 31680-22-5 2,2'-Oxybisbenzoesaeure-dimethylester 
• 37424-29-6 2,2'-oxybis(benzoic acid) 
• 32852-70-3 2,2'-oxy-di-benzoyl chloride 

Downstream Products

• 42916-32-5 11,23-dibenzyl-11,12,23,24-tetrahydro-10H,22H-5,17-dioxa-11,23-diaza-tetrabenzo[a,d,i,l]cyclohexadecene 
• 32636-07-0 6-benzyl-6,7-dihydro-5H-dibenzo[b,g][1,5]oxazocine 
• 606936-80-5 2,2'-bis(diphenylphosphinomethyl)diphenyl ether 
• 1356966-99-8 O(C₆H₄CH₂SH)2 
• 1443037-55-5 C₉₈H₁₄₆OP₄ 
• 79946-21-7 N,N'-ditosyldibenzo-(b,h)-tetrahydro-1,5,6-oxadiazonine 
• 122603-80-9 2,2'-bis(aminomethyl)-diphenyl ether 
• 4731-34-4 2,2'-dimethyldiphenyl ether 
• 132103-21-0 2,2'-oxybisbenzeneacetonitrile 
• 79946-22-8 N,N'-dibenzenosulfonyldibenzo-(b,h)-tetrahydro-1,5,6-oxadiazonine 
• 79946-23-9 N,N'-di-(3,4,5-trimethoxybenzoyl)-dibenzo-(b,h)-tetrahydro-1,5,6-oxadiazonine 
• 79946-24-0 N,N'-dibenzoyl-dibenzo-(b,h)-tetrahydro-1,5,6-oxadiazonine 

Relevant articles and documents

Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands

Nine- and ten-membered N-heterocyclic carbene (NHC) ligands have been developed and for the first time their gold(I) complexes were synthesized. The protonated NHC pro-ligands 2 a–h were prepared by the reaction of readily available N,N′-diarylformamidines with bis-electrophilic building blocks, followed by anion exchange. In situ deprotonation of the tetrafluoroborates 2 a–h with tBuOK in the presence of AuCl(SMe2) provided fast access to NHC-gold(I) complexes 3–10. These new NHC-gold(I) complexes show very good catalytic activity in a cycloisomerization reaction (0.1 mol % catalyst loading, up to 100 % conversion) and their solid-state structures reveal high steric hindrance around the metal atom (%Vbur up to 53.0) which is caused by their expanded-ring architecture.

Study on the intramolecular transannular chalcogen-tin interactions in dithiastannecine compounds

Dithiastannecine compounds of the type [{D(C6H 4CH2S)2}SnR1R2] with different donor atoms D were prepared, where D = O and R1 = R 2 = Ph (4a); R1 = Ph, Rsu

BISPHOSPHINE, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF

Bisphosphines represented by the general formula (I) wherein Ar1 and Ar2 each represents an arylene group which may be substituted; R1 and R2 each represents an alkyl group which may be substituted, or an aryl group which may be substituted, or R1 and R2 may combinedly form a ring together with the phosphorus atom bonded thereto; R3 and R4 each represents hydrogen atom or an alkyl group; and the carbon atoms each having R3 and R4 are bonded in positions ortho to the oxygen atom bonded to Ar1 and Ar2: process for production thereof; Group VIII metal complexes comprising said bisphosphines; and process for producing aldehydes, which comprises, on hydroformylation of ethylenically unsaturated compounds with carbon monoxide and hydrogen, using said Group VIII metal complexes.The hydroformylation of ethylenically unsaturated compounds according to the present invention can produce n-aldehydes at higher reaction rate and industrially more advantageously than with catalysts comprising conventional phosphines, while suppressing side reactions such as hydrogenation and isomerization.