100418-77-7Relevant academic research and scientific papers
UNTERSUCHUNGEN AN DIAZOVERBIDUNGEN UND AZIDEN-XLV ELECTROPHILE DIAZOALKANSUBSTITUTION AN PHOSPHORYLDIAZOMETHANEN MIT THIAPYRYLIUMSALZEN
Khbeis, S. G.,Maas, G.,Regitz, M.
, p. 811 - 817 (2007/10/02)
Electrophilic diazoalkane substitution of the phosphoryl diazomethanes 2a-e with 2,6-di-tert-butylthiapyrylium-tetrafluoroborate (1) yiels the 4-(diazomethyl)-4H-thiapyranes 3a-e; the olefin 5 is formed as by-product in all cases.The μ-allylpalladium chlo
