100428-43-1

Basic information

• Product Name: methyl 12(S)-<(tert-butyldiphenylsilyl)oxy>-5(Z),8(Z),10(E),14(Z)-eicosatetraenoate
• Synonyms: methyl 12(S)-<(tert-butyldiphenylsilyl)oxy>-5(Z),8(Z),10(E),14(Z)-eicosatetraenoate
• CAS NO: 100428-43-1
• Molecular Weight: 572.904
• Mol File: 100428-43-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 12(S)-<(tert-butyldiphenylsilyl)oxy>-5(Z),8(Z),10(E),14(Z)-eicosatetraenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 12(S)-<(tert-butyldiphenylsilyl)oxy>-5(Z),8(Z),10(E),14(Z)-eicosatetraenoate(100428-43-1)
• EPA Substance Registry System: methyl 12(S)-<(tert-butyldiphenylsilyl)oxy>-5(Z),8(Z),10(E),14(Z)-eicosatetraenoate(100428-43-1)

Safety Data

• Hazardous Substances Data: 100428-43-1(Hazardous Substances Data)

Upstream product

• 16666-79-8 hexylidenetriphenylphosphoran 
• 100818-49-3 methyl 12(S)-<(tert-butyldiphenulsilyl)oxy>-14-oxo-5(Z),8(Z),10(E)-tetradecatrienoate 
• 100818-42-6 2-deoxy-3-O-<(tert-butyldiphenylsilyl)oxy>-4,5-dihydroxy-D-erythro-pentose diethyl dithioacetal 
• 100818-44-8 4(S)-<(tert-butyldiphenylsilyl)oxy>-6,6-bis(ethylthio)-hex-2(E)-enal 
• 100818-48-2 methyl 12(S)-<(tert-butyldiphenulsilyl)oxy>-14,14-bis(ethylthio)-5(Z),8(Z),10(E)-tetradecatrienoate 
• 95646-05-2 3(S)-<(tert-butyldiphenylsilyl)oxy>-1,2-bis-O-(isopropylidene)-5(Z)-undecene-1,2(R)-diol 
• 93292-41-2 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal 
• 93292-42-3 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose 
• 100333-62-8 (2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol 
• 131393-01-6 1-(7-iodohept-4Z-enyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane 
• 131392-99-9 1-(7-hydroxyhept-4Z-enyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane 
• 131392-95-5 1-(7-hydroxyhept-4-ynyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane 
• 89276-37-9 1-(pent-4-ynyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane 
• 66348-34-3 2,2-dimethyl-4-oct-2Z-enyl-(S)-1,3-dioxolane 

Downstream Products

• 54397-83-0 12-hydroxyeicosatetraenoic acid 

Relevant articles and documents

A versatile asymmetric synthesis of highly enantiomerically enriched 12(S)-HETE via a combination of enzymatic and chemical processes

This paper describes a versatile asymmetric synthesis of highly enantiomerically enriched 12(S)-HETE via enzymatic kinetic resolution of the key allylic alcohol synthon and the facile introduction of three alkyne units which were concomitantly converted t

Total Synthesis of 8(S)-, 9(S)-, 11(S)-, and 12(S)-HETE Methyl Esters

Starting from D-arabinose, the total syntheses of methyl 8(S)-, 9(S)-, 11(S)-, and 12(S)-hydroxyeicosatetraenoates are described.

A SIMPLE SYNTHESIS OF METHYL 11(S)- AND 12(S)-HETE

Starting from D-arabinose, we describe a synthesis of 11S and 12S-HETE methyl esters.