1004539-50-7Relevant academic research and scientific papers
Synthesis and Characterization of Polycyclic Aromatic Hydrocarbons with Different Spatial Constructions Based on Hexaphenylbenzene Derivatives
Chen, Hua,Zhu, Haoyun,Huang, Yuli,Yang, Junwei,Wang, Weizhi
, p. 3016 - 3026 (2017)
In recent years, low-bandgap polymers have attracted much attention in a wide range of fields. The synthesis of these compounds has been focused on three factors according to the Roncali bandgap theory: 1) the degree of bond-length alternation (Eδr), 2) the aromatic resonance energy of the cycle (ERes), and 3) the substituted groups (ESub). Herein, we have designed and prepared low-bandgap polymers in a different way by using the factors Eθ (the deviation from planarity of the polymer chain) and EInt (the interaction of the molecular chains in the solid state). Thus, three polycyclic aromatic hydrocarbons with different spatial constructions, based on hexaphenylbenzene derivatives, were prepared in this work: linear (P1-OX), V (P2-OX), and zigzag (P3-OX) types. These well-defined polymers exhibited interesting optical and electrochemistry behavior due to their different extents of planarity. Matrix-assisted laser desorption ionization time-of-flight mass spectrometry gave the incremental orderly molecular weight distributions of P1, P2, and P3, the weight-average molecular weights ((Formula presented.)) of which were 9000, 5500, and 69 000, respectively. Their lamellar layer structures and π–π intermolecular stacking were demonstrated by using two-dimensional grazing-incidence X-ray diffraction, which revealed the edge-on chain conformation. Finally, the materials were perfectly adapted to fabricate high-performance organic field-effect transistor devices, which revealed that these compounds could have great prospects as semiconductors.
COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USINGTHE SAME, AND A ELECTRONIC DEVICE THEREOF
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Paragraph 0093; 0094; 0097-0099, (2019/03/30)
Provided in the present invention relates to a new compound improving a light emitting efficiency, a stability, and a life time of a device, an organic electric device using the same, and an electronic apparatus of the same. The organic electric device co
Tribenzopentaphene derivatives with lateral aromatic groups: the effect of the nature and position of substituents on emission properties
Alameddine, Bassam,Anju, Rajamohanan Sobhana,Al-Sagheer, Fakhreia,Jenny, Titus A.
, p. 10363 - 10370 (2016/12/07)
Nine new derivatives of the trapezoidal tribenzopentaphene (TBP) polycyclic aromatic hydrocarbon (PAH) were synthesized via the Suzuki-Miyaura palladium catalyzed cross-coupling reaction. The novel TBP derivatives, which bear various rigid and flexible ar
Bottom-up solution synthesis of narrow nitrogen-doped graphene nanoribbons
Vo, Timothy H.,Shekhirev, Mikhail,Kunkel, Donna A.,Orange, Fran?ois,Guinel, Maxime J.-F.,Enders, Axel,Sinitskii, Alexander
, p. 4172 - 4174 (2014/04/17)
Large quantities of narrow graphene nanoribbons with edge-incorporated nitrogen atoms can be synthesized via Yamamoto coupling of molecular precursors containing nitrogen atoms followed by cyclodehydrogenation using Scholl reaction. the Partner Organisati
Triphenylene-based polymers for blue polymerie light emitting diodes
Saleh, Moussa,Baumgarten, Martin,Mavrinskiy, Alexey,Schaefer, Thomas,Muellen, Klaus
scheme or table, p. 137 - 143 (2011/09/16)
An efficient synthesis has been developed toward a novel series of conjugated blue emitting polymers containing triphenylene as repeating unit for PLEDs. Soluble 1,2,3,4-tetraphenyltriphenylene, 2,3-bis(4-octylphenyl)-l,4- diphenyltriphenylene, 2-heptyl-l
NOVEL POLYMERS
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Page/Page column 44-45, (2008/06/13)
The present invention relates to polymers comprising repeating unit(s) of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In
