1004547-74-3Relevant academic research and scientific papers
Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis: Cp* and Cpt provide complementary selectivity
Hyster, Todd K.,Rovis, Tomislav
, p. 11846 - 11848 (2011/12/02)
The synthesis of pyridines from readily available α,β- unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(iii) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.
Rhodium-catalyzed one-pot synthesis of substituted pyridine derivatives from α,β-unsaturated ketoximes and alkynes
Parthasarathy, Kanniyappan,Jeganmohan, Masilamani,Cheng, Chien-Hong
, p. 325 - 328 (2008/09/19)
(Chemical Equation Presented) A rhodium-catalyzed chelation-assisted C-H activation of α,β-unsaturated ketoximes and the reaction with alkynes to afford highly substituted pyridine derivatives is described.
