1004759-65-2Relevant academic research and scientific papers
Asymmetric Sommelet-Hauser rearrangement of N-benzylic ammonium salts
Tayama, Eiji,Kimura, Hiroshi
, p. 8869 - 8871 (2008/09/19)
(Chemical Equation Presented) [2,3] over [1,2]: The asymmetric Sommelet-Hauser rearrangement of an ammonium salt derived from N-benzylic proline-derived or N-benzylic glycine (-)-8-phenylmenthol ester is shown to proceed with remarkably high levels of stereoselectivity. The method provides unique and efficient access to optically active α-aryl amino acid derivatives.
