1004771-43-0

Basic information

• Product Name: 4-methoxyphenyl 2,3,4-tri-O-acetyl-β-D-glucopyranoside
• Synonyms: 4-methoxyphenyl 2,3,4-tri-O-acetyl-β-D-glucopyranoside
• CAS NO: 1004771-43-0
• Molecular Weight: 412.394
• Mol File: 1004771-43-0.mol

Chemical Properties

• CAS DataBase Reference: 4-methoxyphenyl 2,3,4-tri-O-acetyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl 2,3,4-tri-O-acetyl-β-D-glucopyranoside(1004771-43-0)
• EPA Substance Registry System: 4-methoxyphenyl 2,3,4-tri-O-acetyl-β-D-glucopyranoside(1004771-43-0)

Safety Data

• Hazardous Substances Data: 1004771-43-0(Hazardous Substances Data)

Upstream product

• 2872-65-3 p-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 

Downstream Products

• 1610609-89-6 p-methoxyphenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-acetyl-β-D-glucopyranoside 
• 1610609-85-2 p-methoxyphenyl 2,3,4-tri-O-acetyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranosyl-(1→6)-2,3,4-tri-O-acetyl-β-D-glucopyranoside 
• 1004771-44-1 4-methoxyphenyl 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1->4)-2,3-di-O-acetyl-6-O-benzoyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-acetyl-β-D-glucopyranoside 

Relevant articles and documents

Discriminating non-ylidic carbon-sulfur bond cleavages of sulfonium ylides for alkylation and arylation reactions

A sulfonium ylide participated alkylation and arylation under transition-metal free conditions is described. The disparate reaction pattern allowed the separate activation of non-ylidic S-alkyl and S-aryl bond. Under acidic conditions, sulfonium ylides serve as alkyl cation precursors which facilitate the alkylations. While under alkaline conditions, cleavage of non-ylidic S-aryl bond produces O-arylated compounds efficiently. The robustness of the protocols were established by the excellent compatibility of wide variety of substrates including carbohydrates.