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Carbohydrate-Model Compounds, I. Kinetic and Thermodynamic Effects in Acetal Formation of Enantiomerically Pure Thiolactols
Noe, Christian R.,Knollmueller, Max,Wagner, Ernst,Voellenkle, Horst
, p. 3299 - 3310 (2007/10/02)
The synthesis of the enantiomerically pure thiolactol 1 is described.Depending on reaction conditions either (R)-2 or (S)-2 reacts with preference in acetal formation with racemic 1-phenylethanol (rac-2).
