1004987-40-9

Basic information

• Product Name: 1-[(1S,2R,3R,4R)-3-(3-chlorophenyl)bicyclo[2.2.1]hept-5-en-2-yl]ethanone
• CAS NO: 1004987-40-9
• Molecular Weight: 246.737
• Mol File: 1004987-40-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[(1S,2R,3R,4R)-3-(3-chlorophenyl)bicyclo[2.2.1]hept-5-en-2-yl]ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(1S,2R,3R,4R)-3-(3-chlorophenyl)bicyclo[2.2.1]hept-5-en-2-yl]ethanone(1004987-40-9)
• EPA Substance Registry System: 1-[(1S,2R,3R,4R)-3-(3-chlorophenyl)bicyclo[2.2.1]hept-5-en-2-yl]ethanone(1004987-40-9)

Safety Data

• Hazardous Substances Data: 1004987-40-9(Hazardous Substances Data)

Upstream product

• 20766-36-3 (E)-4-(3-chlorophenyl)but-3-en-2-one 
• 542-92-7 cyclopenta-1,3-diene 

Relevant articles and documents

Oxazaborolidinone-catalyzed enantioselective Diels-Alder reaction of acyclic α,β-unsaturated ketones

(Chemical Equation Presented) allo-Threonine-derived O-acyl-β-phenyl- oxazaborolidinones are demonstrated to be powerful and highly enantioselective Lewis acid catalysts for the Diels-Alder reaction of simple acyclic enone dienophiles, expanding the scope of ketone dienophiles and dienes. With 10 to 20 mol % of catalyst, the Diels-Alder adducts are obtained in 76-98% ee with high endo-selectivity. The catalyst exhibits high activity for the reaction with the less reactive β-substituted dienophiles and the less reactive 1,3-cycohexadiene and 1,3-butadiene derivatives. The application of the catalysts to the Diels-Alder reaction of furan is also described.