1005006-02-9

Basic information

• Product Name: 1-(allyloxy)-4-propoxybenzene
• Synonyms: 1-(allyloxy)-4-propoxybenzene
• CAS NO: 1005006-02-9
• Molecular Weight: 192.258
• Mol File: 1005006-02-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(allyloxy)-4-propoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(allyloxy)-4-propoxybenzene(1005006-02-9)
• EPA Substance Registry System: 1-(allyloxy)-4-propoxybenzene(1005006-02-9)

Safety Data

• Hazardous Substances Data: 1005006-02-9(Hazardous Substances Data)

Upstream product

• 18979-50-5 4-propoxyphenol 
• 106-95-6 allyl bromide 
• 123-31-9 hydroquinone 

Downstream Products

• 1005005-64-0 1-hydroxy-2-allyl-4-propoxybenzene 

Relevant articles and documents

Synthesis and some features of phase behavior of chiral p-alkoxyphenyl glycerol ethers

A series of (S)-3-(4-alkoxyphenoxy)propane-1,2-diols was prepared with the enantiomeric excess 86-92% by Sharpless asymmetric dihydroxylation of 1-alkoxy-4-allyloxybenzenes with an AD-mix-β mixture. R-Enantiomers with enantiomeric excess 97-99% and racemic samples were obtained by reaction of sodium p-substituted phenolates with (R)- and rac-3-chloropropane-1,2-diol. The phase behavior of racemates and scalemates in the produced homolog series of glycerol aryl ethers with hydrocarbon substituents of various length was examined by means of thermomicroscopy. The higher memberes of the homolog series of both racemic and scalemic diols undergo at heating an enantiotropic phase transition to a smectic liquid crystal phase.

Dialkoxybenzene and dialkoxyallylbenzene feeding and oviposition deterrents against the cabbage looper, trichoplusia ni: Potential insect behavior control agents

The antifeedant, oviposition deterrent, and toxic effects of individual dialkoxybenzene compounds/sets and of hydroxy- or alkoxy-substituted allylbenzenes, obtained through Claisen rearrangement of substituted allyloxybenzenes, were assessed against the cabbage looper, Trichoplusia ni, in laboratory bioassays. Most of the compounds/sets strongly deterred larval feeding, with some exhibiting mild toxic and oviposition deterrent effects as well. Some of the compounds/sets were more active than the commercial insect repellent, DEET (N,N-diethyl-m-toluamide), as both feeding and oviposition deterrents against the cabbage looper. On the basis of the obtained oviposition data a general hypothesis was proposed regarding the oviposition sites: one binding mode with the alkyl and allyl groups on the same side of the benzene ring resulted in deterrence, the other with alkyl and allyl groups on opposite sides of the benzene ring resulted in stimulation. The results suggest some structure-activity relationships useful in improving the efficacy of the compounds and designing new, nontoxic insect control agents for agriculture.