100508-05-2

Upstream product

• 100507-98-0 trans-1,5,5-Trimethyl-3-(4-methylphenylsulfonyloxy)cyclohexanol 
• 38756-67-1 2,3-epoxy-3,5,5-trimethylcyclohexanone oxime 

Downstream Products

• 100508-07-4 1,5,5-Trimethyl-cis-3-(methylamino)-r-1-cyclohexanol 

Relevant academic research and scientific papers

Reduction of epoxy isophorone oxime by metal hydrides

Epoxy isophorone oxime (1) is reduced with LiAlH4/CeCl3/THF or NaBH4/MoO3/MeOH to a mixture of t-3-amino-1,5,5-trimethyl-r-1-cyclohexanol (2) and c-3-amino-1,5,5-trimethyl-r-1-cyclohexanol (3), 39:61 and 67:33,

Syntheses and Conformational Properties of Stereoisomeric 1,3-Cyclohexanediol and 3-Aminocyclohexanol Derivatives. X-Ray Structure Analysis of trans-1,3-Dihydroxy-1,5,5-trimethylcyclohexane and c-3-Amino-r-1-hydroxy-1,5,5-trimethylcyclohexane

Solvomercuration of cyclohexenols 3 and 4 yields the respective cis/trans-diols 1a and pure trans-diol 2a.Via the monotosylates the analogous cis-diol cis-2a as well as the cis-amino alcohols cis-1b and cis-2b are prepared diastereomerically pure in good