1005150-78-6

Basic information

• Product Name: methyl (2R,3R)-3-(4-methylphenyl)bicyclo[2.2.1]hept-5-en-2-ylglyoxylate
• CAS NO: 1005150-78-6
• Molecular Weight: 270.328
• Mol File: 1005150-78-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (2R,3R)-3-(4-methylphenyl)bicyclo[2.2.1]hept-5-en-2-ylglyoxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2R,3R)-3-(4-methylphenyl)bicyclo[2.2.1]hept-5-en-2-ylglyoxylate(1005150-78-6)
• EPA Substance Registry System: methyl (2R,3R)-3-(4-methylphenyl)bicyclo[2.2.1]hept-5-en-2-ylglyoxylate(1005150-78-6)

Safety Data

• Hazardous Substances Data: 1005150-78-6(Hazardous Substances Data)

Upstream product

• 100518-76-1 methyl (phenylmethylidene)pyruvate 
• 542-92-7 cyclopenta-1,3-diene 
• 100518-76-1 methyl (E)-2-oxo-4-(4-methylphenyl)but-3-enoate 

Relevant articles and documents

Peri- and enantioselectivity of thermal, scandium-, and [Pybox/Scandium]-catalyzed diels-alder and hetero-diels-alder reactions of methyl (E)-2-Oxo-4-aryl-butenoates with cyclopentadiene

The cycloaddition between methyl (E)-2-oxo-4-aryl-3-butenoates (2a-d) and cyclopentadiene, in addition to the expected normal Diels-Alder (DA) adducts endo-3a-d and exo-4a-d, gives the less expected endo-5a-d products of the [4 + 2] heteroDiels-Alder (HDA