100520-02-3Relevant academic research and scientific papers
Highly selective anti-Markovnikov addition of thiols to vinyl ethers under solvent- and catalyst-free conditions
Lou, Feng-Wen,Xu, Jian-Ming,Liu, Bo-Kai,Wu, Qi,Pan, Qian,Lin, Xian-Fu
, p. 8815 - 8818 (2008/03/18)
A simple and efficient protocol for the anti-Markovnikov addition of thiols to vinyl ethers under solvent- and catalyst-free conditions has been established. A series of thiol ethers containing oxygen atom were obtained with good to excellent yields.
SYNTHESIS OF VINYLCYCLOPENTANES FROM VINYLCYCLOPROPANES AND ALKENES PROMOTED BY BENZENETHIYL RADICAL
Miura, Katsukiyo,Fugami, Keigo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 5135 - 5138 (2007/10/02)
The reaction of dimethyl 2-vinylcyclopropane-1,1-dicarboxylate with butyl vinyl ether in the presence of a catalytic amount of PhSH provides dimethyl 3-butoxy-4-vinylcyclopentane-1,1-dicarboxylate in 82percent yield.
