1005385-36-3Relevant academic research and scientific papers
Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C= SR2
Pascual, Sergio,Asay, Matthew,Illa, Ona,Kato, Tsuyoshi,Bertrand, Guy,Saffon-Merceron, Nathalie,Branchadell, Vicenc,Baceiredo, Antoine
, p. 9078 - 9080 (2008/09/20)
Mixing it up: The first persistent mixed phosphorus-sulfur bisylide has been synthesized (see scheme). Its formation was clearly demonstrated by its chemical reactivity, such as by methylation and complexation with CuI ions. DFT calculations on a model compound indicate that they are highly polarized species as a result of the interaction of the lone pairs of electrons on the central carbon atom with only the phosphonium function. (Chemical Equation Presented).
