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1005391-33-2

[C6H5CH2C(Si(CH3)3)(GaCl2)2]2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1005391-33-2 Structure

  • Basic information

    1. Product Name: [C6H5CH2C(Si(CH3)3)(GaCl2)2]2
    2. Synonyms: [C6H5CH2C(Si(CH3)3)(GaCl2)2]2
    3. CAS NO:1005391-33-2
    4. Molecular Formula:
    5. Molecular Weight: 915.183
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1005391-33-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [C6H5CH2C(Si(CH3)3)(GaCl2)2]2(CAS DataBase Reference)
    10. NIST Chemistry Reference: [C6H5CH2C(Si(CH3)3)(GaCl2)2]2(1005391-33-2)
    11. EPA Substance Registry System: [C6H5CH2C(Si(CH3)3)(GaCl2)2]2(1005391-33-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1005391-33-2(Hazardous Substances Data)

1005391-33-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1005391-33-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,0,5,3,9 and 1 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1005391-33:
(9*1)+(8*0)+(7*0)+(6*5)+(5*3)+(4*9)+(3*1)+(2*3)+(1*3)=102
102 % 10 = 2
So 1005391-33-2 is a valid CAS Registry Number.

1005391-33-2Relevant articles and documents

Twofold hydrogallation of C≡C triple bonds by H-GaCl2 - Synthesis of chelating Lewis acids and their application in adduct formation

Uhl, Werner,Claesener, Michael

, p. 729 - 735 (2008/10/09)

The twofold addition of Ga-H to C≡C triple bonds (hydrogallation) did not succeed by treatment of alkynes with an excess of dialkylgallium hydrides. In contrast, double hydrogallation was easily achieved by the reactions of H-GaCl2 with trimethylsilyl-substituted alkynes [trimethylsilylphenylethyne and 1,4-bis(trimethylsilylethynyl)benzene] in appropriate stoichiometric ratios. The monoalkyne yielded the compound [H 5C6-CH2-C(SiMe3)(GaCl 2)2]2, 1, which was only sparingly soluble in n-hexane. Crystal structure determination revealed a dimeric formula unit possessing two parallel Ga2Cl2 heterocycles in the solid state. Treatment of the dialkyne with four equivalents of the hydride gave a colorless precipitate, which was completely insoluble in hydrocarbons. Addition of diethyl ether to both products afforded soluble and monomelic etherates 1(OEt2)2 and 2 in which the two or four gallium atoms, respectively, were coordinated by ether molecules. Preliminary experiments with simple Lewis bases showed the principle capability of 1 to act as an effective chelating Lewis acid. Adducts of the type [H5C6-CH 2-C(SiMe3)(GaCl2)(GaClX)(μ-Cl)]- (4-6) resulted upon treatment with halide ions (X = Cl, Br, I).

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