1005488-25-4Relevant academic research and scientific papers
Asymmetric synthesis of 2-alkyl-4-hydroxycyclohex-2-en-1-ones by scandium(III) triflate-catalyzed fragmentation of 2-alkyl-3-iodo-1-oxocyclohexan-2,4-carbolactones
Matsuo, Jun-ichi,Kawano, Mizuki,Takeuchi, Kosuke,Tanaka, Hiroyuki,Ishibashi, Hiroyuki
scheme or table, p. 1917 - 1919 (2009/08/17)
Fragmentation of (2S,3S,4S)-2-allyl-3-iodo-1-oxocyclohexan-2,4-carbolactone to (4S)-2-allyl-4-hydroxycyclohex-2-en-1-one, a chiral building block of (-)-platensimycin, proceeded efficiently by using scandium(III) triflate in DMF-H2O (1:3) at 10
A convergent synthesis of the tricyclic core of the dictyosphaeric acids
Barfoot, Christopher W.,Burns, Alan R.,Edwards, Michael G.,Kenworthy, Martin N.,Ahmed, Mahmood,Shanahan, Stephen E.,Taylor, Richard J. K.
, p. 353 - 356 (2008/09/19)
(Chemical Equation Presented) The first synthetic route to the tricyclic core of the dictyosphaeric acids has been established starting from readily available (S)-(-)-4-(tert-butyldimethylsilyloxy)cyclohexenone and involving 9 steps, including a ring-clos
