100553-56-8

Basic information

• Product Name: 3-{[(2Z)-2-(nitromethylidene)imidazolidin-1-yl]methyl}pyridine
• CAS NO: 100553-56-8
• Molecular Formula: C₁₀H₁₂N₄O₂
• Molecular Weight: 220.2279
• Mol File: 100553-56-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 408.3°C at 760 mmHg
• Flash Point: 200.8°C
• Density: 1.369g/cm³
• Vapor Pressure: 7.06E-07mmHg at 25°C
• Refractive Index: 1.672
• CAS DataBase Reference: 3-{[(2Z)-2-(nitromethylidene)imidazolidin-1-yl]methyl}pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-{[(2Z)-2-(nitromethylidene)imidazolidin-1-yl]methyl}pyridine(100553-56-8)
• EPA Substance Registry System: 3-{[(2Z)-2-(nitromethylidene)imidazolidin-1-yl]methyl}pyridine(100553-56-8)

Safety Data

• Hazardous Substances Data: 100553-56-8(Hazardous Substances Data)

Upstream product

• 3099-31-8 nicotinyl chloride 
• 500-22-1 3-pyridinecarboxaldehyde 
• 100553-75-1 N-(3-pyridinylmethyl)-1,2-ethandiamine 
• 13623-94-4 1,1-di(methylsulfanyl)-2-nitroethylene 

Downstream Products

• 1254942-07-8 (Z)-N-[2-nitro-2-[1-(3-pyridinylmethyl)-2-imidazolidinylidene]thioacetyl]benzamide 
• 1254942-14-7 (Z)-N-[2,3-dihydro-7-nitro-1-(3-pyridinylmethyl)-1H-imidazo[1,2-b]isothiazol-6-ylidene]benzamide 

Relevant articles and documents

Design, synthesis, and bioactivity of cyanonitrovinyl neonicotinoids as potential insecticides

A series of cyanonitrovinyl neonicotinoids were designed and synthesized via five steps in about 35% overall yields. All compounds were structurally characterized by 1H nuclear magnetic resonance (NMR), 13C NMR, infrared (IR), and high-resolution mass spectrometry (HRMS), and single-crystal X-ray diffraction analysis of 2-[1-[(6-chloropyridin-3-yl)methyl] -2-imidazolidinylidene]-2-nitroacetonitrile revealed that the double bond is (E)-configured. The preliminary agriculture bioassay indicated that one compound exhibited moderate insecticidal activity against pea aphid. Springer-Verlag 2010.

Structural Modification of the 6-Chloropyridyl Moiety in the Imidacloprid Skeleton: Introduction of a Five-membered Heteroaromatic Ring and the Resulting Insecticidal Activity

-