100571-08-2Relevant academic research and scientific papers
Influence of elemental sulfur on the de-novo-synthesis of organochlorine compounds from residual carbon on fly ash
Bechtler,Stieglitz,Zwick,Will,Roth,Hedwig
, p. 2261 - 2278 (1998)
Thermal experiments between 300°C and 500°C were performed with fly ash of a municipal waste incineration plant which had been spiked with elemental sulfur. The influence of elemental sulfur on the heterogeneous carbon-decomposition and the de-novo-synthesis of polychlorinated compounds was investigated. Compounds such as polychlorinated dibenzodioxins, dibenzofurans, benzenes, benzoand dibenzothiophenes, Cl4-thiophene, Cl4- thienothiophene, Cl7- and Cl8-phenylthiophene were quantified. Apart from those, other intermediate structures were determined. These compounds are mainly aromatics with a vinyl- or butadienyl-group, stabilized by perchlorination. In detail, the compounds are Cl7- and Cl8-styrene, Cl10-vinylnaphthalenes, Cl10-phenylbutadiene, Cl10-octatetraene, Cl10-bis-butadienylsulfides and Cl12-stilbenes.
Synthesis and Chemical Behavior of Perchlorophenylacetylene
Ballester, Manuel,Castaner, Juan,Riera, Juan,Tabernero, Ignacio
, p. 1413 - 1419 (2007/10/02)
Perchlorophenylacetylene (6) is synthesized in three steps: (1) vicinal reductive dechlorination of perchlorostyrene (1) to (pentachlorophenyl)acetylene (2), (2) conversion of 2 into its silver acetylide (7), and (3) chlorination of 7 to 6.Some thermal an
