100573-40-8

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 623-49-4 ethyl cyanoformate 
• 151-50-8 potassium cyanide 
• 541-41-3 chloroformic acid ethyl ester 

Downstream Products

• 100573-22-6 C₁₃H₁₂LiNO₃ 
• 100573-47-5 (Z)-(3-Cyan-1-phenyl-2-propenyl)-ethyl-carbonat 
• 100573-46-4 (E)-(3-Cyan-1-phenyl-2-propenyl)-ethyl-carbonat 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 100573-41-9 (E)-(3-Cyan-1-phenyl-2-butenyl)-ethyl-carbonat 
• 100573-42-0 (Z)-(3-Cyan-1-phenyl-2-butenyl)-ethyl-carbonat 
• 100573-38-4 <1-Cyan-1-(methoxycarbonyl)-3-phenyl-2-propenyl>-ethyl-carbonat 
• 100573-37-3 (1-Cyan-1-(2-phenylethenyl)-3-butenyl)-ethyl-carbonat 
• 100573-36-2 (1-Cyan-1-methyl-3-phenyl-2-propenyl)-ethyl-carbonat 

Relevant academic research and scientific papers

Neutral π-nucleophile-catalyzed cyanation of aldehydes and ketones

1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, a neutral π-nucleophile, was found to be able to efficiently catalyze the cyanation (cyanosilylation and cyanocarbonation) of various aldehydes and ketones, and this study provided the first illustration of u

Trimethylsilyl Cyanide - A Reagent for Umpolung, XI. On the Ambident Character of Substituted Allylic Anions.

The dependence of the α/γ-ratio of alkylation products on several factors has been determined with 1-cyano-3-aryl-1-(trimethylsiloxy)allylic anions.Increasing amounts of γ-product are found in more polar solvents, with larger alkali ions, on addition of HMPT, with smaller alkyl groups in the electrophile, and especially with p-cyanophenyl groups.In contrast, temperature and leaving groups have minor effects.On substitution of the O-silyl group by O-methyl and O-ethoxycarbonyl, α-alkylation predominates strongly.The results are compared to known allylic anions.Furthermore, the isomerisation of compounds of type C to type B is described as well as a new addition reaction of cyanoformates to aldehydes.