1005795-07-2Relevant academic research and scientific papers
Tandem carbon-carbon and carbon-chlorine bond formation by Cu(II) chloride-promoted [3,3] sigmatropic rearrangement of N-allylhydrazones
Mundal, Devon A.,Lee, Jennifer J.,Thomson, Regan J.
, p. 1148 - 1149 (2008)
A new copper(II) chloride-promoted rearrangement of N-allylhydrazones has been developed. Treatment of a number of aromatic N-allylhydrazones with copper(II) chloride provides the formation of both a new carbon-carbon bond and a carbon-chlorine bond in the same reaction. Substrate studies revealed that the carbon-carbon bond-forming step proceeds by way of a concerted [3,3] sigmatropic rearrangement and selectively generates trans-substituted alkenes. Copyright
