100603-20-1

Basic information

• Product Name: PtH(P(C₆H₁₁)3)2(OCH(CO₂C₂H₅)2)
• CAS NO: 100603-20-1
• Molecular Weight: 932.117
• Mol File: 100603-20-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PtH(P(C₆H₁₁)3)2(OCH(CO₂C₂H₅)2)(CAS DataBase Reference)
• NIST Chemistry Reference: PtH(P(C₆H₁₁)3)2(OCH(CO₂C₂H₅)2)(100603-20-1)
• EPA Substance Registry System: PtH(P(C₆H₁₁)3)2(OCH(CO₂C₂H₅)2)(100603-20-1)

Safety Data

• Hazardous Substances Data: 100603-20-1(Hazardous Substances Data)

Upstream product

• 824391-83-5 trans-dihydridobis(tricyclohexylphosphine)platinum 
• 609-09-6 Diethyl ketomalonate 

Downstream Products

• 55664-33-0 bis(tricyclohexylphosphine)platinum⁽⁰⁾ 
• 100647-60-7 Pt(P(C₆H₁₁)3)2(CH₃OCCO₂C₂H₅) 
• 100603-19-8 diethyloxomalonatebis(tricyclohexylphosphine)platinum 
• 100647-58-3 PtH(P(C₆H₁₁)3)2(O(CCHC(CH₃)(CO₂C₂H₅)OCO)) 

Relevant articles and documents

PALLADIUM AND PLATINUM COMPLEXES OF α-KETOESTERS. CRYSTAL STRUCTURE OF

The reactions of M(PCy3)2 (3) (a, M=Pd; b, M=Pt; Cy=cyclohexyl) and trans-PtH2(PCy3)2 (4) with the α-ketoesters diethyloxomalonate (1) and ethylpyruvate (2) have been investigated.At room temperature 1 coordinates strongly to 3, whereas 2 yields labile adducts.At higher temperatures 2 reacts with 3b to yield the enolate (8), the structure of which has been determined by X-ray diffraction.The ester 1 behaves like CO2 in undergoing rapid insertion into the Pt-H bond of 4.Unexpectedly reaction of 2 with 1 does not yield an insertion product, but again gives complex 8.