100638-89-9

Upstream product

• 16361-14-1 2-benzyloxymethylfuran 
• 6295-06-3 butyl glyoxalate 

Downstream Products

• 100638-91-3 butyl 2-(5-benzyloxymethyl-2-furyl)-O-(tetrahydropyran-2-yl)glycolate 
• 100638-97-9 1,7-di-O-benzyl-3,4-dideoxy-α-DL-hept-3-en-2-ulopyranos-5-ulose 
• 100638-97-9 1,7-di-O-benzyl-3,4-dideoxy-β-DL-hept-3-en-2-ulopyranos-5-ulose 
• 100638-93-5 2-benzyloxymethyl-5-<2-benzyloxy-1-(tetrahydropyran-2-yloxy)ethyl>furan 
• 100638-96-8 2-(2-benzyloxy-1-hydroxyethyl)-5-benzyloxymethyl-2,5-dimethoxy-2,5-dihydrofuran 
• 100638-94-6 2-benzyloxymethyl-5-(2-benzyloxy-1-hydroxyethyl)furan 
• 100638-92-4 2-benzyloxymethyl-5-<2-hydroxy-1-(tetrahydropyran-2-yloxy)ethyl>furan 

Relevant academic research and scientific papers

Highly enantioselective synthesis of 2-furanyl-hydroxyacetates from furans via the Friedel-Crafts reaction

(Chemical Equation Presented) The Friedel-Crafts reaction of alkyl glyoxylates with variously substituted furans was found to be efficiently catalyzed under simple, undemanding conditions by a 6,6′-dibromo-BINOL/ Ti(IV) complex with high enantioselectivity. The reaction afforded chiral substituted 2-furanyl-hydroxyacetic acid esters, compounds of high synthetic interest, in good yield and enantiomeric excess, in most examples in the range of 90-97%.

TOTAL SYNTHESIS OF HIGHER-CARBON SUGARS: SYNTHESIS OF METHYL 3,4,5-TRI-O-ACETYL-1,7-DI-O-BENZYL-α-DL-gluco-HEPT-2-ULOPYRANOSIDE

2-(2-Benzyloxy-1-hydroxyethyl)-5-benzyloxymethylfuran