100645-99-6Relevant academic research and scientific papers
FLUOROALIPHATIC ESTERS OF FLUOROSULFONIC ACID. 2. REACTION BIS(FLUOROSULFATO)PERFLUOROALKANES WITH CESIUM FLUORIDE
Rogovik, V. M.,Delyagina, N. I.,Mysov, E. I.,Cherstkov, V. F.,Sterlin, S. R.,German, L. S.
, p. 1870 - 1876 (2007/10/02)
2,3-Bis(fluorosulfato)perfluoroalkanes split under the action of CsF in the absence of solvents, giving a mixture of α-fluorosulfatoperfluoro ketones, perfluoroalkene sulfates, and perfluoro α-diketones.The occurence of these reactions in solutions results mainly in the formation of oxides of the corresponding fluoroolefins or products of their conversions.The reactions carried out are the first examples of nucleophilic substitution at a secondary carbon atom in a perfluorinated saturated chain.
ALKYLATION OF PERFLUORO-2-METHYL-2-PENTYLCARBANION WITH ALKYL AND ALLYL HALIDES
Dmowski, Wojciech,Wozniacki, Ryszard
, p. 385 - 394 (2007/10/02)
Perfluoro-2-methyl-2-pentylcarbanion, generated from perfluoro-4-methyl-2-pentene in an aprotic solvent, reacted with halides RX, where R = alkyl or allyl and X = I, Br, or Cl, to give fluorohydrocarbons of the general formula CF3CF2CF2C(CF3)2R.No reaction with iso-propyl iodide and with 1-iodo-2,2,2-trifluoroethane occured.The reaction with 1-iodo-3,3,3-trifluoropropane resulted in the formation of 3,3,3-trifluoropropene and 2-H-perfluoro-2-methylpentane.
