1006727-97-4Relevant academic research and scientific papers
Gold(I)-Catalyzed Cascade Cyclization of Anilines with Diynes: Controllable Formation of Eight-Membered Ring-Fused Indoles and Propellane-Type Indolines
Yamaguchi, Ayuta,Inuki, Shinsuke,Tokimizu, Yusuke,Oishi, Shinya,Ohno, Hiroaki
, p. 2543 - 2559 (2020)
Heterocycle-fused indoles or indolines are distributed widely in a variety of natural products, bioactive agents, and pharmaceuticals. Herein, we describe the development of gold-catalyzed cascade reactions of anilines with diynes to form eight-membered r
Synthesis of 2-(buta-1,3-diynyl)-N,N-dimethylanilines Using Reductive Methylation Step
Kulyashova, Alexandra E.,Mikheeva, Elena V.,Danilkina, Natalia A.,Balova, Irina A.
, p. 102 - 104 (2014/04/17)
Synthesis of 2-(buta-1,3-diynyl)-N,N-dimethylanilines based on reductive methylation of ortho-iodoanilines using CH2O-NaBH3CN and coupling with terminal diacetylens was developed. Altered sequence including dimethylation of 2-(buta-1,3-diynyl)anilines was
A new route to indolines by the cu-catalyzed cyclization reaction of 2-ethynylanilines with sulfonyl azides
Yoo, Eun Jeong,Chang, Sukbok
supporting information; experimental part, p. 1163 - 1166 (2009/04/06)
It is revealed that 2-sulfonyliminoindolines can be efficiently synthesized by the Cu-catalyzed cyclization reaction of N-alkyl-or aryl-substituted 2-ethynylanilines with sulfonyl azides. This new route to the indoline derivatives is characterized by mild
