100675-80-7Relevant academic research and scientific papers
Substituent Effects on ESR Parameters of α-Phenyl-N-tert-butylnitrone Spin Adducts. Resolution Enhancement and Mass Spectrometry
Pan, Kai,Lin, Chiou-Rong,Ho, Tong-Ing
, p. 632 - 638 (1993)
The combination of high-performance liquid chromatography (HPLC) and ESR spectrometry was used to isolate the free radicals produced by the reaction of a Grignard reagent with 15 substituted α-phenyl-N-tert-butylnitrones.Long-range hyperfine splitting con
Substituent Effect on the Spin-trapping Reactions of Substituted N-Benzylidene-t-butylamine N-oxides
Murofushi, Katsumi,Abe, Kazuhisa,Hirota, Minoru
, p. 1829 - 1834 (2007/10/02)
Relative rates of the reactions of substituted N-benzylidene-t-butylamine N-oxides with substituted phenyl free radicals have been determined by e.s.r. spectroscopic analyses of the products from competitive addition reactions.The substituent effect was interpreted in terms of a reaction mechanism involving an electron-transfer interaction between the reactants.The results are in accord with semiempirical MO calculations.
