100702-46-3Relevant academic research and scientific papers
Lewis acid-catalyzed Friedel-Crafts reactions toward highly versatile, α-quaternary oxime ethers
Schlegel, Marcel,Schneider, Christoph
, p. 11124 - 11127 (2018/10/24)
The synthesis of all-carbon-substituted, quaternary stereocenters through Lewis acid-catalyzed Friedel-Crafts alkylation of cyclic and acyclic 2-hydroxy oxime ethers proceeds under mild reaction conditions and with high yields. Moreover, the oxime ether m
Regioreversed Allylation in Lewis Acid-mediated and Photochemical Addition Reactions of Unsymmetric α-Diketones with Allylic Stannanes
Takuwa, Akio,Nishigaichi, Yutaka,Yamashita, Koichi,Iwamoto, Hidetoshi
, p. 1761 - 1764 (2007/10/02)
In the photochemical reaction of allyl- and benzyltrimethylstannanes with unsymmetric α-diketones (PhCOCOR), the allylic group was introduced to the benzoyl carbon in high or excellent selectivity, whereas the acyl carbon was allylated either exclusively
