100703-67-1Relevant academic research and scientific papers
Arynic Condensatiopn of Ketone Enolates. 17. New General Access to Benzocyclobutene Derivatives
Gregoire, Brigitte,Carre, Marie-Christiane,Caubere, Paul
, p. 1419 - 1427 (1986)
Arynic condensation of 1,2-diketone monoketal enolates appeared to be a very simple way to synthesize benzocyclobutene derivatives.X-ray diffraction and 1H NMR spectra allowed us to determine the structure of the new compounds and to propose a mechanism concerning these condensations.Finally, during this work we devised a new and easily performed two-step synthesis of 1,2-diketones.
