100716-77-6Relevant academic research and scientific papers
Iron(III) chloride-catalyzed synthesis of 3-carboxy-2,5-disubstituted furans from γ-alkynyl aryl- and alkylketones
Golonka, Alexander N.,Schindler, Corinna S.
, p. 4109 - 4114 (2017)
A mild, catalytic method for the synthesis of 3-carboxy-2,5-disubstituted furans is reported proceeding via a 5-exo-dig cycloisomerization reaction. The iron(III) chloride-catalyzed transformation of aryl- and alkyl β-ketoesters enables synthetic access t
Fe(II)/Au(I) Relay Catalyzed Propargylisoxazole to Pyridine Isomerization: Access to 6-Halonicotinates
Galenko, Alexey V.,Shakirova, Firuza M.,Galenko, Ekaterina E.,Novikov, Mikhail S.,Khlebnikov, Alexander F.
, p. 5367 - 5379 (2017)
An efficient synthesis of methyl nicotinates/6-halonicotinates by the domino isomerization of 4-propargyl/(3-halopropargyl)-5-methoxyisoxazoles under Fe(II)/Au(I) relay catalysis was developed. It was found that FeNTf2 is an effective catalyst
