100717-47-3

Upstream product

• 100-61-8 N-methylaniline 
• 98272-31-2 2-[1-Hydroxy-meth-(Z)-ylidene]-5-methyl-cyclopentanone 
• 1120-72-5 2-Methylcyclopentanone 

Downstream Products

• 405877-15-8 (R)-(+)-2-methyl-2-phenyl-5-(N-methylanilinomethylene)cyclopentanone 
• 350249-56-8 (R)-(-)-2-methyl-2-(trans-1-propenyl)-5-(N-methyl-anilinomethylene)-cyclopentanone 
• 847974-25-8 2-(4-t-butylphenyl)-2-methyl-5-(N-methyl-anilinomethylene)-cyclopentanone 
• 847974-27-0 2-(4-Methoxyphenyl)2-methyl-5-(N-methyl-anilinomethylene)-cyclopentanone 
• 847974-30-5 2-(3-Tolyl)-2-methyl-5-(N-methyl-anilinomethylene)cyclopentanone 
• 847974-31-6 2-(2-Tolyl)-2-methyl-5-(N-methyl-anilinomethylene)-cyclopentanone 
• 847974-32-7 2-(4-Trifluoromethylphenyl)-2-methyl-5-(N-methyl-anilinomethylene)-cyclopentanone 
• 847974-34-9 2-(4-cyanophenyl)-2-methyl-5-(N-methyl-anilinomethylene)-cyclopentanone 

Relevant academic research and scientific papers

An improved catalyst for the asymmetric arylation of ketone enolates

A new catalyst system for the enantioselective α-arylation of ketones is reported. This catalyst, prepared from Pd2(dba)3 and a bulky dialkylphosphino-binaphthyl ligand, is able to effect the asymmetric arylation of ketone enolates w

Catalytic asymmetric vinylation of ketone enolates.

[see reaction]. A protocol for the catalytic asymmetric vinylation of ketone enolates has been developed. Key to the success of this process was the development of new electron-rich chiral monodentate ligands.