1007222-55-0Relevant academic research and scientific papers
Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes
Munro-Leighton, Colleen,Delp, Samuel A.,Alsop, Nikki M.,Blue, Elizabeth D.,Gunnoe, T. Brent
, p. 111 - 113 (2008/09/19)
Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition of the amido/thiolate ligand of (IPr)Cu(XR) (X = NH or S; R = Ph, CH2Ph) to free vinylarene. The Royal Society of Chemistry.
